
CEMCA - UMR CNRS 6521
Université de Bretagne Occidentale -
Faculté des Sciences et Techniques -
6 Avenue Victor le Gorgeu, CS 93837, 29238 BREST CEDEX 3 - FRANCE
Dr. Frédéric GLOAGUEN
Directeur de Recherche
Pôle Communication, SPECTRE
bureau C229
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Publications Récentes
Article dans une revue
2023
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- Marc Bourrez, Frédéric Gloaguen. Electrochemical reduction and protonation of a biomimetic diiron azadithiolate hexacarbonyl complex: Mechanistic insights. Bioelectrochemistry, 2023, 153, pp.108488. ⟨10.1016/j.bioelechem.2023.108488⟩. ⟨hal-04132478⟩
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- Jean-François Cornet, Jérémi Dauchet, Fabrice Gros, Thomas Vourc’h, Frédéric Gloaguen. Production d'hydrogène solaire par photosynthèse artificielle. Les Techniques de l'Ingenieur, 2023, Techniques de l'ingénieur, RE405. ⟨hal-04081924⟩
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2022
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- Gema Pérez, Guillermo Díaz-Sainz, Lucía Gómez-Coma, Lucía Álvarez-Miguel, Aymeric Garnier, et al.. Rhodium-based cathodes with ultra-low metal loading to increase the sustainability in the hydrogen evolution reaction. Journal of Environmental Chemical Engineering, 2022, 10 (3), pp.107682. ⟨10.1016/j.jece.2022.107682⟩. ⟨hal-03648091⟩
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2021
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- Carlos Garcia Bellido, Lucia Álvarez-Miguel, Daniel Miguel, Noémie Lalaoui, Nolwenn Cabon, et al.. Electrochemically‐driven reduction of carbon dioxide mediated by mono‐reduced Mo‐diimine tetracarbonyl complexes: electrochemical, spectroelectrochemical and theoretical studies. ChemElectroChem, 2021, 8 (10), pp.1899-1910. ⟨10.1002/celc.202100359⟩. ⟨hal-03213553⟩
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- Simone Bertini, Motiar Rahaman, Abhijit Dutta, Philippe P. Schollhammer, Alexander Rudnev, et al.. Oxo-functionalised mesoionic NHC nickel complexes for selective electrocatalytic reduction of CO 2 to formate. Green Chemistry, 2021, ⟨10.1039/D1GC00388G⟩. ⟨hal-03210579⟩
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- Juan Corredor, Dulanjan Harankahage, Frédéric Gloaguen, Maria Rivero, Mikhail Zamkov, et al.. Influence of QD photosensitizers in the photocatalytic production of hydrogen with biomimetic [FeFe]-hydrogenase. Comparative performance of CdSe and CdTe. Chemosphere, 2021, 278, pp.130485. ⟨10.1016/j.chemosphere.2021.130485⟩. ⟨hal-03197033⟩
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2020
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- Pradip Ghosh, Sander de Vos, Martin Lutz, Frederic Gloaguen, Philippe P. Schollhammer, et al.. Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C–H Bond in H2 Formation. Chemistry - A European Journal, 2020, ⟨10.1002/chem.201905746⟩. ⟨hal-02564719⟩
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- Claudie Miry, Emmanuel Ngameni, Frédéric Gloaguen, Maurice L’her. Why Cobalt macrocyclic complexes are not efficient catalysts for the oxygen reduction reaction, under acidic conditions. Electrochimica Acta, 2020, 358, pp.136854. ⟨10.1016/j.electacta.2020.136854⟩. ⟨hal-02939303⟩
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2019
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- Juan Corredor, María J. Rivero, C. M. Rangel, Frederic Gloaguen, Inmaculada Ortiz. Comprehensive review and future perspectives on the photocatalytic hydrogen production: Comprehensive review and future perspectives on the photocatalytic hydrogen production. Journal of Chemical Technology and Biotechnology, 2019, 94 (10), pp.3049--3063. ⟨10.1002/jctb.6123⟩. ⟨hal-02283959⟩
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- Christoph Steinlechner, Arend Roesel, Elisabeth Oberem, Ayla Päpcke, Nils Rockstroh, et al.. Selective Earth-Abundant System for CO 2 Reduction: Comparing Photo- and Electrocatalytic Processes. ACS Catalysis, 2019, 9 (3), pp.2091-2100. ⟨10.1021/acscatal.8b03548⟩. ⟨hal-02146794⟩
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- Laurianne Wojcik, Isidoro López, Sebastien Gauthier, Nolwenn Cabon, Pascal Le Poul, et al.. Insights into the radical-radical and radical-substrate dimerization processes for substituted phenylmethylenepyrans. Electrochimica Acta, 2019, 305, pp.304-311. ⟨10.1016/j.electacta.2019.03.046⟩. ⟨hal-02096108⟩
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2018
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- Caroline Supplis, Fabrice Gros, Ghiles Dahi, Jérémi Dauchet, Matthieu Roudet, et al.. Spectral radiative analysis of bio-inspired H2 production in a benchmark photoreactor: A first investigation using spatial photonic balance. International Journal of Hydrogen Energy, 2018, 43 (17), pp.8221-8231. ⟨10.1016/j.ijhydene.2018.03.097⟩. ⟨hal-02700111⟩
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2017
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- Ramona Kositzki, Stefan Mebs, Nils Schuth, Nils Leidel, Lennart Schwartz, et al.. Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry. Dalton Transactions, 2017, 46 (37), pp.12544 - 12557. ⟨10.1039/C7DT02720F⟩. ⟨hal-01624338⟩
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- Laurianne Wojcik, François Michaud, Sebastien Gauthier, Nolwenn Cabon, Pascal Le Poul, et al.. Reversible redox switching of chromophoric phenylmethylenepyrans by carbon-carbon bond making/breaking. Journal of Organic Chemistry, 2017, 82 (23), pp.12395 - 12405. ⟨10.1021/acs.joc.7b02199⟩. ⟨hal-01624342⟩
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2016
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- Frederic Gloaguen. Electrochemistry of Simple Organometallic Models of Iron–Iron Hydrogenases in Organic Solvent and Water. Inorganic Chemistry, 2016, 55 (2), pp.390 - 398. ⟨10.1021/acs.inorgchem.5b02245⟩. ⟨hal-01539195⟩
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- G. Nguyen Vien, Stéphane Rioual, Frederic Gloaguen, B. Rouvellou, Benoit Lescop. Study of the magnetization behavior of ferromagnetic nanowire array: Existence of growth defects revealed by micromagnetic simulations. Journal of Magnetism and Magnetic Materials, 2016, 401, pp.378 - 385. ⟨10.1016/j.jmmm.2015.10.070⟩. ⟨hal-01539198⟩
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- Stéphane Rioual, Benoit Lescop, Francois Quentel, Frederic Gloaguen. Molecular material based on electropolymerized cobalt macrocycle for electrocatalytic hydrogen evolution . Physical Chemistry Chemical Physics, 2016. ⟨hal-01322706⟩
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2015
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- Marc Bourrez, Frederic Gloaguen. Application of the energetic span model to the electrochemical catalysis of proton reduction by a diiron azadithiolate complex. New Journal of Chemistry, 2015, 39 (10), pp.8073 - 8079. ⟨10.1039/C5NJ00770D⟩. ⟨hal-01538593⟩
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- Marc Bourrez, Frederic Gloaguen. Electrochemical and Computational Study of the Reactivity of a Diiron Azadithiolate Complex towards Protons in the Presence of Coordinating Anions. European Journal of Inorganic Chemistry, 2015, 2015 (30), pp.4986 - 4990. ⟨10.1002/ejic.201500675⟩. ⟨hal-01538594⟩
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- Marc Bourrez, Romain Steinmetz, Sascha Ott, Frederic Gloaguen, Leif Hammarström. Concerted proton-coupled electron transfer from a metal-hydride complex. Nature Chemistry, 2015, 7 (2), pp.140 - 145. ⟨10.1038/nchem.2157⟩. ⟨hal-01532306⟩
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- Stéphane Rioual, Benoit Lescop, François Quentel, Frederic Gloaguen. A molecular material based on electropolymerized cobalt macrocycle for electrocatalytic hydrogen evolution. Physical Chemistry Chemical Physics, 2015, 17, pp.13374--13379. ⟨10.1039/c5cp01210d⟩. ⟨hal-02283958⟩
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Communication dans un congrès
2018
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- Caroline Supplis, Fabrice Gros, Jérémi Dauchet, Matthieu Roudet, Frédéric Gloaguen, et al.. Spectral radiative analysis of bio-inspired H2 production. SPEA10 Conference, Jun 2018, Almeria, Spain. ⟨hal-01915581⟩
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Autre publication scientifique
2020
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- Pradip Ghosh, Sander Vos, Martin Lutz, Frederic Gloaguen, Philippe Schollhammer, et al.. Cover Feature: Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H 2 Formation (Chem. Eur. J. 55/2020). 2020, pp.12490-12490. ⟨10.1002/chem.202003332⟩. ⟨hal-04186839⟩
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Poster de conférence
2018
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- Caroline Supplis, Fabrice Gros, Jérémi Dauchet, Matthieu Roudet, Frédéric Gloaguen, et al.. Analyse radiative spectrale de la production bio-inspirée d'hydrogène. 10th Colloque Franco-Roumain de Chimie Appliquée (COFrRoCA 2018), Jun 2018, Bacau, Romania. ⟨hal-01915587⟩
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Pré-publication, Document de travail
2015
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- Francois Quentel, Frederic Gloaguen. Kinetic and thermodynamic aspects of the electrocatalysis of acid reduction in organic solvent using molecular diiron-dithiolate compounds. 2015. ⟨hal-01130667⟩
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Publications Antérieures
Article dans une revue
2014
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- Marc Bourrez, Romain Steinmetz, Frederic Gloaguen. Mechanistic Insights into the Catalysis of Electrochemical Proton Reduction by a Diiron Azadithiolate Complex. Inorganic Chemistry, 2014, 53 (19), pp.10667 - 10673. ⟨10.1021/ic501815m⟩. ⟨hal-01535888⟩
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- Christophe Orain, François Quentel, Frederic Gloaguen. Photocatalytic Hydrogen Production Using Models of the Iron-Iron Hydrogenase Active Site Dispersed in Micellar Solution. ChemSusChem, 2014, ChemSusChem, 7 (2), pp.638 - 643. ⟨10.1002/cssc.201300631⟩. ⟨hal-01529407⟩
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2013
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- Lin Chen, Mei Wang, Kai Han, Peili Zhang, Frederic Gloaguen, et al.. A super-efficient cobalt catalyst for electrochemical hydrogen production from neutral water with 80 mV overpotential. Energy & Environmental Science, 2013, 7 (1), pp.329 - 334. ⟨10.1039/C3EE42194E⟩. ⟨hal-01529568⟩
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- Lin Chen, Mei Wang, Frederic Gloaguen, Dehua Zheng, Peili Zhang, et al.. Tetranuclear Iron Complexes Bearing Benzenetetrathiolate Bridges as Four-Electron Transformation Templates and Their Electrocatalytic Properties for Proton Reduction. Inorganic Chemistry, 2013, 52 (4), pp.1798--1806. ⟨10.1021/ic301647u⟩. ⟨hal-02283956⟩
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- Antoine Perhirin, Edouard Kraffe, Yanic Marty, Francois Quentel, Philippe Elies, et al.. Electrochemistry of cytochrome c immobilized on cardiolipin-modified electrodes: a probe for protein – lipid interactions. BBA - Biochimica et Biophysica Acta, 2013, 1830 (3), pp.2798-2803. ⟨10.1016/j.bbagen.2012.12.009⟩. ⟨hal-01130700⟩
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- E. Planes, Frédéric Gloaguen, N. Alberola, L. Flandin. Spatial distribution of the electrical conductivity in highly filled polymers: Experiment, modeling, and application to bipolar plates. Journal of Applied Physics, 2013, 114 (22), ⟨10.1063/1.4841155⟩. ⟨hal-01890812⟩
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- Peili Zhang, Mei Wang, Frederic Gloaguen, Lin Chen, François Quentel, et al.. Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes. Chemical Communications, 2013, 49, pp.9455--9457. ⟨10.1039/c3cc43491e⟩. ⟨hal-02283957⟩
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2012
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- Lin Chen, Mei Wang, Frederic Gloaguen, Dehua Zheng, Peili Zhang, et al.. Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes. Chemistry - A European Journal, 2012, 18 (44), pp.13968 - 13973. ⟨10.1002/chem.201201326⟩. ⟨hal-01556801⟩
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- François Quentel, Guillaume Passard, Frederic Gloaguen. Electrochemical hydrogen production in aqueous micellar solution by a diiron benzenedithiolate complex relevant to [FeFe] hydrogenases. Energy & Environmental Science, 2012, 5 (7), ⟨10.1039/C2EE21531D⟩. ⟨hal-01559120⟩
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- François Quentel, Guillaume Passard, Frederic Gloaguen. A Binuclear Iron-Thiolate Catalyst for Electrochemical Hydrogen Production in Aqueous Micellar Solution. Chemistry - A European Journal, 2012, 18 (42), pp.13473 - 13479. ⟨10.1002/chem.201201884⟩. ⟨hal-01556797⟩
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2011
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- Kévin Charreteur, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Diiron Complexes with a [2Fe3S] Core Related to the Active Site of [FeFe]H2ases. European Journal of Inorganic Chemistry, 2011, 2011 (7), pp.1038 - 1042. ⟨10.1002/ejic.201000984⟩. ⟨hal-01577032⟩
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- Dounia Chouffai, Giuseppe Zampella, Jean-François Capon, Luca de Gioia, Frederic Gloaguen, et al.. Oxidatively Induced Reactivity of [Fe 2 (CO) 4 (κ 2 -dppe)(μ-pdt)]: an Electrochemical and Theoretical Study of the Structure Change and Ligand Binding Processes. Inorganic Chemistry, 2011, 50 (24), pp.12575 - 12585. ⟨10.1021/ic201601q⟩. ⟨hal-01561135⟩
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- A. Ghaddar, Frederic Gloaguen, J. Gieraltowski, C. Tannous. Magnetic crossover effect in Nickel nanowire arrays. Physica B: Condensed Matter, 2011, 406 (10), pp.2046 - 2053. ⟨10.1016/j.physb.2011.03.021⟩. ⟨hal-01577225⟩
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- Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, 2011, 47 (3), pp.878 - 880. ⟨10.1039/C0CC03295F⟩. ⟨hal-01577005⟩
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2010
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- Kévin Charreteur, Mohamed Kdider, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. Effect of Electron-Withdrawing Dithiolate Bridge on the Electron-Transfer Steps in Diiron Molecules Related to [2Fe] H Subsite of the [FeFe]-Hydrogenases. Inorganic Chemistry, 2010, 49 (5), pp.2496 - 2501. ⟨10.1021/ic902401k⟩. ⟨hal-01577276⟩
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- A Ghaddar, Frederic Gloaguen, J Gieraltowski. Magnetic properties of ferromagnetic nanowire arrays: Theory and experiment. Journal of Physics: Conference Series, 2010, 200 (7), ⟨10.1088/1742-6596/200/7/072032⟩. ⟨hal-01577348⟩
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- Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Reactivity of [Fe 2 (CO) 6 (μ-S 2 )] toward a Base-Containing Diphosphine (Ph 2 PCH 2 ) 2 NCH 3 : Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph 2 PCH 2 N(CH 3 )CH 2 S) and Bidentate Thiophosphinito (Ph 2 PS = PS) Bridges. Organometallics, 2010, 29 (5), pp.1296 - 1301. ⟨10.1021/om9011054⟩. ⟨hal-01577278⟩
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- Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Investigation on the protonation of a trisubstituted [Fe(2)(CO)(3)(PPh(3))(kappa(2)-phen)(mu-pdt)] complex: rotated versus unrotated intermediate pathways.. Inorganic Chemistry, 2010, 49 (11), pp.5003-8. ⟨10.1021/ic100108h⟩. ⟨hal-00737677⟩
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- Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Tuning of electron transfer in diiron azo-bridged complexes relevant to hydrogenases. International Journal of Hydrogen Energy, 2010, 35 (19), pp.10797 - 10802. ⟨10.1016/j.ijhydene.2010.02.111⟩. ⟨hal-01577363⟩
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- Youtao Si, Kévin Charreteur, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. Non-innocent bma ligand in a dissymetrically disubstituted diiron dithiolate related to the active site of the [FeFe] hydrogenases. Journal of Inorganic Biochemistry, 2010, 104 (10), pp.1038 - 1042. ⟨10.1016/j.jinorgbio.2010.05.011⟩. ⟨hal-01577400⟩
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2009
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- Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases. Coordination Chemistry Reviews, 2009, 253 (9-10), pp.1476 - 1494. ⟨10.1016/j.ccr.2008.10.020⟩. ⟨hal-01578087⟩
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- Salah Ezzaher, Jean-François Capon, Nicolas Dumontet, Frederic Gloaguen, François Y. Pétillon, et al.. Electrochemical study of the role of a H-bridged, unsymmetrically disubstituted diiron complex in proton reduction catalysis. Journal of Electroanalytical Chemistry, 2009, 626 (1-2), pp.161 - 170. ⟨10.1016/j.jelechem.2008.12.005⟩. ⟨hal-01578082⟩
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- Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe] H Subsite of [FeFe]H 2 ase. Inorganic Chemistry, 2009, 48 (1), pp.2 - 4. ⟨10.1021/ic801369u⟩. ⟨hal-01580262⟩
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- A. Ghaddar, J. Gieraltowski, Frederic Gloaguen, R. Żuberek, P. Aleshkevych, et al.. Thermal Evolution of Magnetic Interactions in Ni Nanowires Embedded in Polycarbonate Membranes by Ferromagnetic Resonance. Acta Physica Polonica A, 2009, 116 (6), pp.1039 - 1043. ⟨10.12693/APhysPolA.116.1039⟩. ⟨hal-01580295⟩
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- Abbas Ghaddar, Jacek Gieraltowski, Frederic Gloaguen. Effects of anodization and electrodeposition conditions on the growth of copper and cobalt nanostructures in aluminum oxide films. Journal of Applied Electrochemistry, 2009, 39 (5), pp.719 - 725. ⟨10.1007/s10800-008-9715-z⟩. ⟨hal-01580203⟩
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- Frederic Gloaguen, Thomas B. Rauchfuss. Small molecule mimics of hydrogenases: hydrides and redox. Chemical Society Reviews, 2009, 38 (1), pp.100 - 108. ⟨10.1039/B801796B⟩. ⟨hal-01578063⟩
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- Didier Morvan, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand. Journal of Organometallic Chemistry, 2009, 694 (17), pp.2801 - 2807. ⟨10.1016/j.jorganchem.2009.01.018⟩. ⟨hal-01580265⟩
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2008
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- Jean-François Capon, Salah Ezzaher, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase. Chemistry - A European Journal, 2008, 14 (6), pp.1954 - 1964. ⟨10.1002/chem.200701454⟩. ⟨hal-01580430⟩
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- ref_biblio
- Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Organometallic Diiron Complex Chemistry Related to the [2Fe] H Subsite of [FeFe]H 2 ase. European Journal of Inorganic Chemistry, 2008, 2008 (30), pp.4671 - 4681. ⟨10.1002/ejic.200800717⟩. ⟨hal-01580468⟩
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- ref_biblio
- Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase. Comptes Rendus. Chimie, 2008, 11 (8), pp.842 - 851. ⟨10.1016/j.crci.2008.03.007⟩. ⟨hal-01580511⟩
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- Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the FeFe H(2)ase. Comptes Rendus. Chimie, 2008, 11 (8), pp.842-851. ⟨hal-00456300⟩
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- Salah Ezzaher, Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site. Chemical Communications, 2008, 22, ⟨10.1039/B801373J⟩. ⟨hal-01580431⟩
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- Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, Nelly Kervarec, François Y. Pétillon, et al.. Diiron chelate complexes relevant to the active site of the iron-only hydrogenase. Comptes Rendus. Chimie, 2008, 11 (8), pp.906 - 914. ⟨10.1016/j.crci.2008.04.002⟩. ⟨hal-01580508⟩
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- Didier Morvan, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin, et al.. Phosphorus Functionalized Carbenes: Synthesis and Coordination Properties. Phosphorus, Sulfur, and Silicon and the Related Elements, 2008, 183 (2-3), pp.669 - 670. ⟨10.1080/10426500701796306⟩. ⟨hal-01580438⟩
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- Matthew T. Olsen, Aaron K. Justice, Frederic Gloaguen, Thomas B. Rauchfuss, Scott R. Wilson. New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases. Inorganic Chemistry, 2008, 47 (24), pp.11816 - 11824. ⟨10.1021/ic801542w⟩. ⟨hal-01580530⟩
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2007
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- Jean-François Capon, Salah Ezzaher, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electrochemical and theoretical investigations of the reduction of [Fe2(CO)5L{µ-SCH2XCH2S}] complexes related to [FeFe] hydrogenase. New Journal of Chemistry, 2007, 31 (12), ⟨10.1039/B709273C⟩. ⟨hal-01581409⟩
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- Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electron-Transfer-Catalyzed Rearrangement of Unsymmetrically Substituted Diiron Dithiolate Complexes Related to the Active Site of the [FeFe]-Hydrogenases. Inorganic Chemistry, 2007, 46 (23), pp.9863 - 9872. ⟨10.1021/ic701327w⟩. ⟨hal-01581411⟩
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- ref_biblio
- Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site Mimic. Inorganic Chemistry, 2007, 46 (9), pp.3426 - 3428. ⟨10.1021/ic0703124⟩. ⟨hal-01581352⟩
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- ref_biblio
- Frederic Gloaguen, Didier Morvan, Jean-François Capon, Philippe P. Schollhammer, Jean Talarmin. Electrochemical proton reduction at mild potentials by monosubstituted diiron organometallic complexes bearing a benzenedithiolate bridge. Journal of Electroanalytical Chemistry, 2007, 603 (1), pp.15 - 20. ⟨10.1016/j.jelechem.2007.02.003⟩. ⟨hal-01581346⟩
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- ref_biblio
- Didier Morvan, Jean-François Capon, Frederic Gloaguen, Alan Le Goff, Mathieu Marchivie, et al.. N-Heterocyclic Carbene Ligands in Nonsymmetric Diiron Models of Hydrogenase Active Sites. Organometallics, 2007, 26 (8), pp.2042 - 2052. ⟨10.1021/om061173l⟩. ⟨hal-01581322⟩
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- ref_biblio
- Didier Morvan, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Electrochemical Synthesis of Mono- and Disubstituted Diiron Dithiolate Complexes as Models for the Active Site of Iron-Only Hydrogenases. European Journal of Inorganic Chemistry, 2007, 2007 (32), pp.5062 - 5068. ⟨10.1002/ejic.200700598⟩. ⟨hal-01581372⟩
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- ref_biblio
- Pierre-Yves Orain, Jean-François Capon, Nelly Kervarec, Frederic Gloaguen, François Y. Pétillon, et al.. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site. Dalton Transactions, 2007, 34, ⟨10.1039/B709287C⟩. ⟨hal-01581437⟩
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- ref_biblio
- Vijendran Vijaikanth, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase. Journal of Organometallic Chemistry, 2007, 692 (19), pp.4177 - 4181. ⟨10.1016/j.jorganchem.2007.06.042⟩. ⟨hal-01581390⟩
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2006
- ref_biblio
- Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Activation of proton by the two-electron reduction of a di-iron organometallic complex. Journal of electroanalytical chemistry and interfacial electrochemistry, 2006, 595 (1), pp.47-52. ⟨10.1016/j.jelechem.2006.06.005⟩. ⟨hal-00700128⟩
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2005
- ref_biblio
- Jean-François Capon, S.E. Hassnaoui, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site. Organometallics, 2005, 24 (9), pp.2020-2022. ⟨10.1021/om049132h⟩. ⟨hal-01763739⟩
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- ref_biblio
- Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Catalysis of the electrochemical H2 evolution by di-iron sub-site models. Coordination Chemistry Reviews, 2005, 249 (15-16 SPEC. ISS.), pp.1664-1676. ⟨10.1016/j.ccr.2004.11.018⟩. ⟨hal-01763762⟩
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- ref_biblio
- V. Vijaikanth, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Chemically modified electrode based on an organometallic model of the [FeFe] hydrogenase active center. Electrochemistry Communications, 2005, 7 (4), pp.427-430. ⟨10.1016/j.elecom.2005.02.019⟩. ⟨hal-01763738⟩
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2004
- ref_biblio
- Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Electrochemical proton reduction by thiolate-bridged hexacarbonyldiiron clusters. Journal of Electroanalytical Chemistry, 2004, 566 (2), pp.241-247. ⟨10.1016/j.jelechem.2003.11.032⟩. ⟨hal-01763872⟩
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- ref_biblio
- P. Das, Jean-François Capon, Frederic Gloaguen, François Pétillon, Philippe P. Schollhammer, et al.. Di-iron aza diphosphido complexes: Mimics for the active site of Fe-only hydrogenase, and effects of changing the coordinating atoms of the bridging ligand in [Fe2μ-(ECH2)2NR(CO)6]. Inorganic Chemistry, 2004, 43 (26), pp.8203-8205. ⟨10.1021/ic048772+⟩. ⟨hal-01763877⟩
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2003
- ref_biblio
- Frédéric Maillard, Frédéric Gloaguen, Jean-Michel Léger. Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles. Journal of Applied Electrochemistry, 2003, 33 (1), pp. 1-8. ⟨10.1023/A:1022906615060⟩. ⟨hal-00417976⟩
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- ref_biblio
- Frédéric Maillard, Frederic Gloaguen, Françoise Hahn, Jean-Michel Léger. Electrooxidation of Carbon Monoxide at Ruthenium-Modified Platinum Nano-particles: Evidence for CO Surface Mobility. Fuel Cells, 2003, 2 (3-4), pp. 143-152. ⟨10.1002/fuce.200290013⟩. ⟨hal-00417973⟩
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2002
- ref_biblio
- Frédéric Gloaguen, J. D. Lawrence, T. B. Rauchfuss, M. Benard, M. M. Rohmer. Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases. Inorganic Chemistry, 2002, 41 (25), pp.6573--6582. ⟨10.1021/ic025838x⟩. ⟨hal-02283979⟩
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- ref_biblio
- Frédéric Maillard, M. Martin, Frédéric Gloaguen, Jean-Michel Léger. Oxygen electroreduction on carbon-supported platinum catalysts. Particle-size effect on the tolerance to methanol competition. Electrochimica Acta, 2002, 47 (21), pp. 3431-3440. ⟨10.1016/S0013-4686(02)00279-7⟩. ⟨hal-00418091⟩
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2001
- ref_biblio
- P. Convert, C. Coutanceau, P. Crouigneau, Frédéric Gloaguen, C. Lamy. Electrodes modified by electrodeposition of CoTAA complexes as selective oxygen cathodes in a direct methanol fuel cell. Journal of Applied Electrochemistry, 2001, 31 (9), pp.945--952. ⟨10.1023/a:1017596408165⟩. ⟨hal-02283974⟩
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- ref_biblio
- Frédéric Gloaguen, J. D. Lawrence, T. B. Rauchfuss. Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate. Journal of the American Chemical Society, 2001, 123 (38), pp.9476--9477. ⟨10.1021/ja016516f⟩. ⟨hal-02283975⟩
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- ref_biblio
- Frédéric Gloaguen, J. D. Lawrence, M. Schmidt, S. R. Wilson, T. B. Rauchfuss. Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x]x- as active site models for Fe-only hydrogenases. Journal of the American Chemical Society, 2001, 123 (50), pp.12518--12527. ⟨10.1021/ja016071v⟩. ⟨hal-02283976⟩
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- ref_biblio
- F. Vigier, Frédéric Gloaguen, J. M. Leger, C. Lamy. Electrochemical and spontaneous deposition of ruthenium at platinum electrodes for methanol oxidation: an electrochemical quartz crystal microbalance study. Electrochimica Acta, 2001, 46 (28), pp.4331--4337. ⟨10.1016/s0013-4686(01)00680-6⟩. ⟨hal-02283977⟩
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2000
- ref_biblio
- C. Rice, Y. Tong, E. Oldfield, A. Wieckowski, F. Hahn, et al.. In situ infrared study of carbon monoxide adsorbed onto commercial fuel-cell-grade carbon-supported platinum nanoparticles: Correlation with C-13 NMR results. Journal of Physical Chemistry B, 2000, 104 (24), pp.5803--5807. ⟨10.1021/jp0007179⟩. ⟨hal-02283973⟩
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1999
- ref_biblio
- Frédéric Gloaguen, J. M. Leger, C. Lamy. An electrochemical quartz crystal microbalance study of the hydrogen underpotential deposition at a Pt electrode. Journal of Electroanalytical Chemistry, 1999, 467 (1-2), pp.186--192. ⟨10.1016/s0022-0728(98)00448-3⟩. ⟨hal-02283971⟩
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- ref_biblio
- Frédéric Gloaguen, J. M. Leger, C. Lamy, A. Marmann, U. Stimming, et al.. Platinum electrodeposition on graphite: electrochemical study and STM imaging. Electrochimica Acta, 1999, 44 (11), pp.1805--1816. ⟨10.1016/s0013-4686(98)00332-6⟩. ⟨hal-02283972⟩
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1998
- ref_biblio
- Frédéric Gloaguen, P. Convert, S. Gamburzev, O. A. Velev, S. Srinivasan. An evaluation of the macro-homogeneous and agglomerate model for oxygen reduction in PEMFCs. Electrochimica Acta, 1998, 43 (24), pp.3767--3772. ⟨10.1016/s0013-4686(98)00136-4⟩. ⟨hal-02283970⟩
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1997
- ref_biblio
- Frédéric Gloaguen, J. M. Leger, C. Lamy. Electrocatalytic oxidation of methanol on platinum nanoparticles electrodeposited onto porous carbon substrates. Journal of Applied Electrochemistry, 1997, 27 (9), pp.1052--1060. ⟨10.1023/a:1018434609543⟩. ⟨hal-02283969⟩
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- ref_biblio
- Frédéric Gloaguen, R. Durand. Simulations of PEFC cathodes: an effectiveness factor approach. Journal of Applied Electrochemistry, 1997, 27 (9), pp.1029--1035. ⟨10.1023/a:1018478324564⟩. ⟨hal-02283968⟩
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1996
- ref_biblio
- A. Gamez, D. Richard, P. Gallezot, Frédéric Gloaguen, R. Faure, et al.. Oxygen reduction on well-defined platinum nanoparticles inside recast ionomer. Electrochimica Acta, 1996, 41, pp.307--314. ⟨10.1016/0013-4686(95)00305-X⟩. ⟨hal-02285008⟩
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- ref_biblio
- A. Gamez, D. Richard, P. Gallezot, Frédéric Gloaguen, R. Faure, et al.. Oxygen reduction on well-defined platinum nanoparticles inside recast ionomer. Electrochimica Acta, 1996, 41, pp.307-314. ⟨hal-00006371⟩
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1995
- ref_biblio
- D. Aberdam, R. Durand, R. Faure, Frédéric Gloaguen, J. L. Hazemann, et al.. X-ray-absorption near-edge structure study of the electrooxidation reaction of CO on Pt50Ru50 nanoparticles. Journal of Electroanalytical Chemistry, 1995, 398 (1-2), pp.43--47. ⟨10.1016/0022-0728(95)04140-4⟩. ⟨hal-02283967⟩
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1994
- ref_biblio
- Frédéric Gloaguen, F. Andolfatto, R. Durand, P. Ozil. Kinetic-study of electrochemical reactions at catalyst-recast ionomer interfaces from thin active layer modeling. Journal of Applied Electrochemistry, 1994, 24 (9), pp.863--869. ⟨10.1007/bf00348773⟩. ⟨hal-02283965⟩
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- ref_biblio
- A. Kabbabi, Frédéric Gloaguen, F. Andolfatto, R. Durand. Particle-size effect for oxygen reduction and methanol oxidation on Pt/C inside a proton-exchange membrane. Journal of Electroanalytical Chemistry, 1994, 373 (1-2), pp.251--254. ⟨10.1016/0022-0728(94)03503-2⟩. ⟨hal-02283966⟩
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1992
- ref_biblio
- M. El Khalifa, J. Y. Saillard, Frédéric Gloaguen, C. Le Floch, F. Y. Petillon, et al.. Theoretical-analysis of the cis/trans electrochemically-induced and CO-catalyzed isomerization reaction of [Mo2cp2(CO)2(µ-SR)2] and its reactivity toward isocyanide ligands. New Journal of Chemistry, 1992, 16 (8-9), pp.847--854. ⟨hal-02283964⟩
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1991
- ref_biblio
- Frédéric Gloaguen, C. Le Floch, F. Y. Petillon, J. Talarmin, M. El Khalifa, et al.. Electrochemistry of dinuclear, thiolate-bridged transition-metal compounds. 7. Electrochemical generation of isomers of [Mo2cp2(CO)2(µ-SMe)2] and their reactivity toward isocyanide ligands. Organometallics, 1991, 10 (6), pp.2004--2011. ⟨10.1021/om00052a056⟩. ⟨hal-02283963⟩
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Chapitre d'ouvrage
2013
- ref_biblio
- V. Artero, Frederic Gloaguen, M. Fontecave, Philippe P. Schollhammer. Biomasse : filière chimique bio-inspirée. R. Mosseri et C. Jeandel. L'énergie à découvert, CNRS Editions, pp.158-159, 2013. ⟨hal-01262161⟩
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1993
- ref_biblio
- Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩
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Rapport
2014
- ref_biblio
- Frederic Gloaguen, François Quentel, B. Lescop, Stéphane Rioual, Jean-François Cornet, et al.. Caractérisation des propriétés photo-électrochimiques et modélisation prédictive du fonctionnement d'une photo-anode IrO2/α-Fe2O3 pour l'oxydation de l'eau. [Rapport de recherche] Laboratoire Cethil. 2014. ⟨hal-01023533⟩
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