Accueil / Annuaire / Philippe SCHOLLHAMMER

 

CEMCA - UMR CNRS 6521
Université de Bretagne Occidentale -
Faculté des Sciences et Techniques -
6 Avenue Victor le Gorgeu, CS 93837, 29238 BREST CEDEX 3 - FRANCE

Pr. Philippe SCHOLLHAMMER

Professeur
CIEl

bureau C351bis

Publications Récentes

Article dans une revue

2023

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Federica Arrigoni, Luca de Gioia, Catherine Elleouet, François Pétillon, Philippe Schollhammer, et al.. Normal vs. Inverted Ordering of Reduction Potentials in [FeFe]‐Hydrogenases Biomimetics: Effect of the Dithiolate Bulk. Chemistry - A European Journal, 2023, ⟨10.1002/chem.202300569⟩. ⟨hal-04108528⟩
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Lucile Chatelain, Federica Arrigoni, Philippe Schollhammer, Giuseppe Zampella. C–Cl Bond Activation at Rotated vs Unrotated Dinuclear Site Related to [FeFe]-Hydrogenases. Inorganic Chemistry, 2023, 62 (51), pp.20913-20918. ⟨10.1021/acs.inorgchem.3c03481⟩. ⟨hal-04373323⟩
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Mohamed Kdider, Catherine Elleouet, François Pétillon, Philippe Schollhammer. Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases. Molbank, 2023, 2023 (3), pp.M1719. ⟨10.3390/M1719⟩. ⟨hal-04209161⟩
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Andrea Mele, Federica Arrigoni, Luca de Gioia, Catherine Elleouet, François Pétillon, et al.. Use of the Asymmetrical Chelating N-Donor 2-Imino-Pyridine as a Redox [Fe4S4] Cubane Surrogate at a Di-Iron Site Related to [FeFe]-Hydrogenases. Inorganics, 2023, 11 (12), pp.463. ⟨10.3390/inorganics11120463⟩. ⟨hal-04373319⟩
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2022

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Lucile Chatelain, Jean-Baptiste Breton, Federica Arrigoni, Philippe Schollhammer, Giuseppe Zampella. Geometrical influence on the non-biomimetic heterolytic splitting of H 2 by bio-inspired [FeFe]-hydrogenase complexes: a rare example of inverted frustrated Lewis pair based reactivity. Chemical Science, 2022, 13 (17), pp.4863-4873. ⟨10.1039/D1SC06975F⟩. ⟨hal-03917902⟩
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Andrea Mele, Federica Arrigoni, Catherine Elleouet, François Pétillon, Philippe Schollhammer, et al.. Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases. Molecules, 2022, 27 (15), pp.4700. ⟨10.3390/molecules27154700⟩. ⟨hal-03917886⟩
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Francesca Realini, Catherine Elleouet, François Y. Pétillon, Philippe P. Schollhammer. Tri‐ and tetra‐substituted derivatives of [Fe2(CO)6(µ‐dithiolate)] as novel dinuclear platforms related to the H‐cluster of [FeFe]H2ases. European Journal of Inorganic Chemistry, 2022, ⟨10.1002/ejic.202200133⟩. ⟨hal-03629176⟩
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2021

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Laith Almazahreh, Federica Arrigoni, Hassan Abul-Futouh, Mohammad El-Khateeb, Helmar Görls, et al.. Proton Shuttle Mediated by (SCH 2 ) 2 P═O Moiety in [FeFe]-Hydrogenase Mimics: Electrochemical and DFT Studies. ACS Catalysis, 2021, pp.7080-7098. ⟨10.1021/acscatal.0c05563⟩. ⟨hal-03251619⟩
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Simone Bertini, Motiar Rahaman, Abhijit Dutta, Philippe P. Schollhammer, Alexander Rudnev, et al.. Oxo-functionalised mesoionic NHC nickel complexes for selective electrocatalytic reduction of CO 2 to formate. Green Chemistry, 2021, 23 (9), pp.3365-3373. ⟨10.1039/D1GC00388G⟩. ⟨hal-03210579⟩
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Ahmad Hobballah, Federica Arrigoni, Catherine Elleouet, Claudio Greco, Maxime Laurans, et al.. Triiron clusters derived from dinuclear complexes related to the active site of [Fe-Fe] hydrogenases: Steric effect of the dithiolate bridge on redox properties, a DFT analysis.. Inorganic Chemistry Frontiers, 2021, ⟨10.1039/D1QI00006C⟩. ⟨hal-03138212⟩
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2020

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Pradip Ghosh, Sander de Vos, Martin Lutz, Frederic Gloaguen, Philippe P. Schollhammer, et al.. Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C–H Bond in H2 Formation. Chemistry - A European Journal, 2020, ⟨10.1002/chem.201905746⟩. ⟨hal-02564719⟩
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Ahmad Hobballah, Rachid Motei, Sondes Lounissi, Catherine Elleouet, François Pétillon, et al.. Synthesis, characterization and electrochemical reductive properties of complexes [Fe2(CO)4(k2-PPh2NR2)(µ-dithiolate)] related to the H-cluster of [FeFe]-H2ases. European Journal of Inorganic Chemistry, In press, ⟨10.1002/ejic.202000824⟩. ⟨hal-02950776⟩
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Andrea Mele, Simone Bertini, Martin Albrecht, Catherine Elleouet, François Pétillon, et al.. A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene. CHIMIA, 2020, 74 (6), pp.499-503. ⟨10.2533/chimia.2020.499⟩. ⟨hal-02902975⟩
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Philippe P. Schollhammer, Federica Arrigoni, Catherine Elleouet, Andrea Mele, François Pétillon, et al.. Insights into the two‐electron reductive process of [FeFe]H2ase biomimetics. Cyclic voltammetry and DFT investigation on chelates control of redox properties of [Fe2(CO)4(κ2‐chelate)(µ‐dithiolate)].. Chemistry - A European Journal, 2020, ⟨10.1002/chem.202003233⟩. ⟨hal-02915936⟩
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2019

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Massinissa Ayad, Philippe P. Schollhammer, Yves Le Mest, Laurianne Wojcik, François Pétillon, et al.. Mononuclear copper(II) complexes containing a macrocyclic ditopic ligand: synthesis, structures and properties. Inorganica Chimica Acta, 2019, 497, pp.119081. ⟨10.1016/j.ica.2019.119081⟩. ⟨hal-02269763⟩
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Solène Bouchard, Maurizio Bruschi, Luca de Gioia, Christine Leroy, François Pétillon, et al.. FeMo Heterobimetallic Dithiolate Complexes: Investigation of Their Electron Transfer Chemistry and Reactivity toward Acids, a Density Functional Theory Rationalization. Inorganic Chemistry, 2019, 58 (1), pp.679-694. ⟨10.1021/acs.inorgchem.8b02861⟩. ⟨hal-01969345⟩
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Maximilian Marx, Andrea Mele, Anke Spannenberg, Christoph Steinlechner, Henrik Junge, et al.. Addressing the Reproducibility of Photocatalytic Carbon Dioxide Reduction. ChemCatChem, 2019, ⟨10.1002/cctc.201901686⟩. ⟨hal-02359680⟩
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2018

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Federica Arrigoni, Salma Mohamed Bouh, Catherine Elleouet, Philippe P. Schollhammer, François Pétillon, et al.. Electrochemical and Theoretical Investigations of the Oxidatively induced reactivity of the complex [Fe2(CO)4(κ2-dmpe)(µ-adtBn)] related to the Active Site of [FeFe]-Hydrogenases. Chemistry - A European Journal, In press, ⟨10.1002/chem.201802980⟩. ⟨hal-01845050⟩
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Massinissa Ayad, Robertus J.M. Klein Gebbink, Yves Le Mest, Philippe P. Schollhammer, Nicolas Le Poul, et al.. Mononuclear iron(II) complexes containing a tripodal and macrocyclic nitrogen ligand: synthesis, reactivity and application in cyclohexane oxidation catalysis. Dalton Transactions, 2018, 47 (43), pp.15596-15612. ⟨10.1039/C8DT02952K⟩. ⟨hal-01885668⟩
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2017

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Hassan Abul-Futouh, Laith R. Almazahreh, Takahiro Sakamoto, Nhu Y. T. Stessman, Dennis L. Lichtenberger, et al.. [FeFe]-Hydrogenase H-Cluster Mimics with Unique Planar μ-(SCH 2 ) 2 ER 2 Linkers (E=Ge and Sn). Chemistry - A European Journal, 2017, 23 (2), pp.346 - 359. ⟨10.1002/chem.201603843⟩. ⟨hal-01624527⟩
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Federica Arrigoni, Salma Mohamed bouh, Luca De gioia, Catherine Elleouet, François Y. Pétillon, et al.. Influence of the Dithiolate Bridge on the Oxidative Processes of Diiron Models Related to the Active Site of [FeFe] Hydrogenases. Chemistry - A European Journal, 2017, 23 (18), pp.4364 - 4372. ⟨10.1002/chem.201605060⟩. ⟨hal-01520734⟩
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Philippe P. Schollhammer, François Y. Pétillon, Jean Talarmin. Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes. Coordination Chemistry Reviews, 2017, 331, pp.73 - 92. ⟨10.1016/j.ccr.2016.10.004⟩. ⟨hal-01485537⟩
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2015

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Laith R. Almazahreh, Wolfgang Imhof, Jean Talarmin, Philippe P. Schollhammer, Helmar Gorls, et al.. Ligand effects on the electrochemical behavior of [Fe2(CO)5(L){μ-(SCH2)2(Ph)P[double bond, length as m-dash]O}] (L = PPh3, P(OEt)3) hydrogenase model complexes . Dalton Transactions, 2015, 44 (16), pp.7177 - 7189. ⟨10.1039/C5DT00064E⟩. ⟨hal-01538592⟩
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Dounia Chouffai, Jean-François Capon, Luca de Gioia, François Y. Pétillon, Philippe P. Schollhammer, et al.. A Diferrous Dithiolate as a Model of the Elusive H ox inact State of the [FeFe] Hydrogenases: An Electrochemical and Theoretical Dissection of Its Redox Chemistry. Inorganic Chemistry, 2015, 54 (1), pp.299 - 311. ⟨10.1021/ic5024746⟩. ⟨hal-01538585⟩
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Roman Goy, Luca Bertini, Catherine Elleouet, Helmar Görls, Giuseppe Zampella, et al.. A sterically stabilized Fe I –Fe I semi-rotated conformation of [FeFe] hydrogenase subsite model. Dalton Transactions, 2015, 44 (4), pp.1690 - 1699. ⟨10.1039/c4dt03223c⟩. ⟨hal-01520732⟩
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Roman Goy, Luca Bertini, Helmar Gorls, Luca de Gioia, Jean Talarmin, et al.. Silicon-Heteroaromatic [FeFe] Hydrogenase Model Complexes: Insight into Protonation, Electrochemical Properties, and Molecular Structures. Chemistry - A European Journal, 2015, 21 (13), pp.5061 - 5073. ⟨10.1002/chem.201406087⟩. ⟨hal-01538589⟩
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Chapitre d'ouvrage

2022

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Catherine Elleouet, François Pétillon, Philippe Schollhammer. Role of a Redox-Active Ligand Close to a Dinuclear Activating Framework. Philippe Kalck. Modes of Cooperative Effects in Dinuclear Complexes, 70, Springer, pp.99-156, 2022, Topics in Organometallic Chemistry, 978-3-031-32249-5. ⟨10.1007/3418_2022_77⟩. ⟨hal-04108533⟩
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2019

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Catherine Elleouet, Philippe P. Schollhammer, François Y. Pétillon. Non-noble metal-based molecular catalysts for proton reduction. Non-Noble Metal Catalysis: Molecular Approaches and Reactions, , Chapitre 19, 2019, 978-3-527-34061-3. ⟨hal-02068897⟩
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2018

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Catherine Elleouet, François Y. Pétillon, Philippe P. Schollhammer. [FeFe]-Hydrogenases Models. Toshikazu Hirao; Toshiyuki Moriuchi. Advances in Bioorganometallic - Chemistry 1st Edition, 1st Edition, Elsevier, pp.347-359, 2018, Advances in Bioorganometallic Chemistry, 9780128141984. ⟨hal-01959850⟩
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2015

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Ulf-Peter Apfel, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, Wolfgang Weigand. [FeFe] Hydrogenase Models: an Overview. Bioinspired Catalysis, Metal-Sulfur Complexes., chapitre 4, Wiley‐VCH, pp.79-104, 2015, Part II : Model Complexes of the Active Site of Hydrogenases-Proton and Dihydrogen Activation, 9783527333080. ⟨10.1002/9783527664160.ch4⟩. ⟨hal-02127128⟩
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Autre publication scientifique

2022

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Francesca Realini, Catherine Elleouet, François Pétillon, Philippe Schollhammer. Cover Feature: Tri‐ and Tetra‐Substituted Derivatives of [Fe 2 (CO) 6 (μ‐dithiolate)] as Novel Dinuclear Platforms Related to the H‐Cluster of [FeFe]H 2 ases (Eur. J. Inorg. Chem. 19/2022). 2022, ⟨10.1002/ejic.202200332⟩. ⟨hal-04186823⟩
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2021

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Ahmad Hobballah, Sondes Lounissi, Rachid Motei, Catherine Elleouet, François Pétillon, et al.. Front Cover: Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe 2 (CO) 4 (κ 2 ‐P Ph 2 N R 2 )( μ ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H 2 ases (Eur. J. Inorg. Chem. 3/2021). 2021, pp.186-186. ⟨10.1002/ejic.202001144⟩. ⟨hal-04186813⟩
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Philippe Schollhammer, François Pétillon, Catherine Elleouet, Claudio Greco, Ahmad Hobballah, et al.. Front cover. 2021, pp.3611-3611. ⟨10.1039/D1QI90058G⟩. ⟨hal-04186886⟩
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2020

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Pradip Ghosh, Sander Vos, Martin Lutz, Frederic Gloaguen, Philippe Schollhammer, et al.. Cover Feature: Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H 2 Formation (Chem. Eur. J. 55/2020). 2020, pp.12490-12490. ⟨10.1002/chem.202003332⟩. ⟨hal-04186839⟩
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Maximilian Marx, Andrea Mele, Anke Spannenberg, Christoph Steinlechner, Henrik Junge, et al.. Front Cover: Addressing the Reproducibility of Photocatalytic Carbon Dioxide Reduction (ChemCatChem 6/2020). 2020, pp.1527-1527. ⟨10.1002/cctc.202000142⟩. ⟨hal-04186844⟩
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Publications Antérieures

Article dans une revue

2014

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Laetitia Beaume, Martin Clémancey, Geneviève Blondin, Claudio Greco, François Y. Pétillon, et al.. New Systematic Route to Mixed-Valence Triiron Clusters Derived from Dinuclear Models of the Active Site of [Fe–Fe]-Hydrogenases. Organometallics, 2014, 33 (22), pp.6290 - 6293. ⟨10.1021/om5010594⟩. ⟨hal-01535887⟩
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Solène Bouchard, Martin Clémancey, Geneviève Blondin, Maurizio Bruschi, Kévin Charreteur, et al.. A New FeMo Complex as a Model of Heterobimetallic Assemblies in Natural Systems: Mössbauer and Density Functional Theory Investigations. Inorganic Chemistry, 2014, 53 (21), pp.11345-11347. ⟨10.1021/ic501875q⟩. ⟨hal-01215528⟩
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Luca de Gioia, Catherine Elleouet, Sabrina Munery, François Y. Pétillon, Philippe P. Schollhammer, et al.. Reductive Behavior of [Fe 2 (CO) 4 (κ 2 -dmpe){μ-(SCH 2 ) 2 NBn}]: Effect of Symmetrization on the Rotated Conformation in Fe I -Fe I Models of [2Fe] H Subsite of [Fe-Fe]­H 2 ases. European Journal of Inorganic Chemistry, 2014, 2014 (22), pp.3456 - 3461. ⟨10.1002/ejic.201402335⟩. ⟨hal-01520730⟩
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Alan Le Goff, David Vénec, Christine Leroy, François Y. Pétillon, Philippe P. Schollhammer, et al.. Acid-Base Control of Hemilabile Proton-Responsive Protecting Devices in Dimolybdenum, Thiolate-Bridged Complexes. Inorganic Chemistry, 2014, 53 (4), pp.2200 - 2210. ⟨10.1021/ic402873c⟩. ⟨hal-01517763⟩
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2013

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Roman Goy, Ulf-Peter Apfel, Catherine Elleouet, Daniel Escudero, Martin Elstner, et al.. A Silicon-Heteroaromatic System as Photosensitizer for Light-Driven Hydrogen Production by Hydrogenase Mimics. European Journal of Inorganic Chemistry, 2013, 2013 (25), pp.4466 - 4472. ⟨10.1002/ejic.201300537⟩. ⟨hal-01520727⟩
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Sabrina Munery, Jean-François Capon, Luca De gioia, Catherine Elleouet, Claudio Greco, et al.. New Fe I -Fe I Complex Featuring a Rotated Conformation Related to the [2 Fe] H Subsite of [Fe-Fe] Hydrogenase. Chemistry - A European Journal, 2013, 19 (46), pp.15458 - 15461. ⟨10.1002/chem.201303316⟩. ⟨hal-01517798⟩
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2012

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Dounia Chouffai, Giuseppe Zampella, Jean-François Capon, Luca De Gioia, Alan Le Goff, et al.. Electrochemical and Theoretical Studies of the Impact of the Chelating Ligand on the Reactivity of [Fe 2 (CO) 4 (? 2 -LL)(?-pdt)] + Complexes with Different Substrates (LL = I Me -CH 2 -I Me , dppe; I Me = 1-Methylimidazol-2-ylidene). Organometallics, 2012, 31 (3), pp.1082 - 1091. ⟨10.1021/om201143p⟩. ⟨hal-01556853⟩
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Sondes Lounissi, Giuseppe Zampella, Jean-François Capon, Luca de Gioia, Fatma Matoussi, et al.. Electrochemical and Theoretical Investigations of the Role of the Appended Base on the Reduction of Protons by [Fe 2 (CO) 4 (? 2 -PNP R )(?-S(CH 2 ) 3 S] (PNP R ={Ph 2 PCH 2 } 2 NR, R=Me, Ph). Chemistry - A European Journal, 2012, 18 (35), pp.11123 - 11138. ⟨10.1002/chem.201201087⟩. ⟨hal-01556886⟩
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2011

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Kévin Charreteur, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Diiron Complexes with a [2Fe3S] Core Related to the Active Site of [FeFe]H2ases. European Journal of Inorganic Chemistry, 2011, 2011 (7), pp.1038 - 1042. ⟨10.1002/ejic.201000984⟩. ⟨hal-01577032⟩
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Dounia Chouffai, Giuseppe Zampella, Jean-François Capon, Luca de Gioia, Frederic Gloaguen, et al.. Oxidatively Induced Reactivity of [Fe 2 (CO) 4 (κ 2 -dppe)(μ-pdt)]: an Electrochemical and Theoretical Study of the Structure Change and Ligand Binding Processes. Inorganic Chemistry, 2011, 50 (24), pp.12575 - 12585. ⟨10.1021/ic201601q⟩. ⟨hal-01561135⟩
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Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, 2011, 47 (3), pp.878 - 880. ⟨10.1039/C0CC03295F⟩. ⟨hal-01577005⟩
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Wilfried-Solo Ojo, John E. Mcgrady, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Thermal Generation and Structures of the Unsaturated Doubly Bridged Complex [Mo 2 Cp 2 Cl 2 (μ-SMe) 2 ] and Its Quadruply Bridged Isomer [Mo 2 Cp 2 (μ-Cl) 2 (μ-SMe) 2 ]. Organometallics, 2011, 30 (3), pp.649 - 652. ⟨10.1021/om101061y⟩. ⟨hal-01577036⟩
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Das Pankaj, Borah Malabika, François Michaud, François Y. Pétillon, Philippe P. Schollhammer. Phosphorus–carbon(pyridyl) bond cleavage on reacting diphenyl-2-pyridylphosphine with triiron dodecacarbonyl. Inorganica Chimica Acta, 2011, ⟨10.1016/j.ica.2011.06.035⟩. ⟨hal-01577236⟩
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2010

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Kévin Charreteur, Mohamed Kdider, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. Effect of Electron-Withdrawing Dithiolate Bridge on the Electron-Transfer Steps in Diiron Molecules Related to [2Fe] H Subsite of the [FeFe]-Hydrogenases. Inorganic Chemistry, 2010, 49 (5), pp.2496 - 2501. ⟨10.1021/ic902401k⟩. ⟨hal-01577276⟩
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Claudio Greco, Piercarlo Fantucci, Luca de Gioia, Ricardo Suarez-Bertoa, Maurizio Bruschi, et al.. Electrocatalytic dihydrogen evolution mechanism of [Fe2(CO)4(κ2-Ph2PCH2CH2PPh2)(μ-S(CH2)3S)] and related models of the [FeFe]-hydrogenases active site: a DFT investigation. Dalton Transactions, 2010, 39 (31), ⟨10.1039/B926040D⟩. ⟨hal-01577405⟩
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Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Reactivity of [Fe 2 (CO) 6 (μ-S 2 )] toward a Base-Containing Diphosphine (Ph 2 PCH 2 ) 2 NCH 3 : Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph 2 PCH 2 N(CH 3 )CH 2 S) and Bidentate Thiophosphinito (Ph 2 PS = PS) Bridges. Organometallics, 2010, 29 (5), pp.1296 - 1301. ⟨10.1021/om9011054⟩. ⟨hal-01577278⟩
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Wilfried-Solo Ojo, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Carbon−Sulfur and Carbon−Halogen Bond Cleavage of Acyclic or Cyclic Thioethers, Thiophenes, and Dihaloalkanes with the Trithiolato-Bridged Cation [Mo 2 Cp 2 (μ-SMe) 3 (MeCN) 2 ] +. Organometallics, 2010, 29 (2), pp.448 - 462. ⟨10.1021/om900901s⟩. ⟨hal-01577275⟩
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Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Investigation on the protonation of a trisubstituted [Fe(2)(CO)(3)(PPh(3))(kappa(2)-phen)(mu-pdt)] complex: rotated versus unrotated intermediate pathways.. Inorganic Chemistry, 2010, 49 (11), pp.5003-8. ⟨10.1021/ic100108h⟩. ⟨hal-00737677⟩
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Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Tuning of electron transfer in diiron azo-bridged complexes relevant to hydrogenases. International Journal of Hydrogen Energy, 2010, 35 (19), pp.10797 - 10802. ⟨10.1016/j.ijhydene.2010.02.111⟩. ⟨hal-01577363⟩
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Youtao Si, Kévin Charreteur, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. Non-innocent bma ligand in a dissymetrically disubstituted diiron dithiolate related to the active site of the [FeFe] hydrogenases. Journal of Inorganic Biochemistry, 2010, 104 (10), pp.1038 - 1042. ⟨10.1016/j.jinorgbio.2010.05.011⟩. ⟨hal-01577400⟩
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2009

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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases. Coordination Chemistry Reviews, 2009, 253 (9-10), pp.1476 - 1494. ⟨10.1016/j.ccr.2008.10.020⟩. ⟨hal-01578087⟩
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Salah Ezzaher, Jean-François Capon, Nicolas Dumontet, Frederic Gloaguen, François Y. Pétillon, et al.. Electrochemical study of the role of a H-bridged, unsymmetrically disubstituted diiron complex in proton reduction catalysis. Journal of Electroanalytical Chemistry, 2009, 626 (1-2), pp.161 - 170. ⟨10.1016/j.jelechem.2008.12.005⟩. ⟨hal-01578082⟩
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Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe] H Subsite of [FeFe]H 2 ase. Inorganic Chemistry, 2009, 48 (1), pp.2 - 4. ⟨10.1021/ic801369u⟩. ⟨hal-01580262⟩
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Didier Morvan, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand. Journal of Organometallic Chemistry, 2009, 694 (17), pp.2801 - 2807. ⟨10.1016/j.jorganchem.2009.01.018⟩. ⟨hal-01580265⟩
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2008

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Jean-François Capon, Salah Ezzaher, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase. Chemistry - A European Journal, 2008, 14 (6), pp.1954 - 1964. ⟨10.1002/chem.200701454⟩. ⟨hal-01580430⟩
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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase. Comptes Rendus. Chimie, 2008, 11 (8), pp.842 - 851. ⟨10.1016/j.crci.2008.03.007⟩. ⟨hal-01580511⟩
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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Organometallic Diiron Complex Chemistry Related to the [2Fe] H Subsite of [FeFe]H 2 ase. European Journal of Inorganic Chemistry, 2008, 2008 (30), pp.4671 - 4681. ⟨10.1002/ejic.200800717⟩. ⟨hal-01580468⟩
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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the FeFe H(2)ase. Comptes Rendus. Chimie, 2008, 11 (8), pp.842-851. ⟨hal-00456300⟩
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Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, Nelly Kervarec, François Y. Pétillon, et al.. Diiron chelate complexes relevant to the active site of the iron-only hydrogenase. Comptes Rendus. Chimie, 2008, 11 (8), pp.906 - 914. ⟨10.1016/j.crci.2008.04.002⟩. ⟨hal-01580508⟩
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Salah Ezzaher, Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site. Chemical Communications, 2008, 22, ⟨10.1039/B801373J⟩. ⟨hal-01580431⟩
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Didier Morvan, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin, et al.. Phosphorus Functionalized Carbenes: Synthesis and Coordination Properties. Phosphorus, Sulfur, and Silicon and the Related Elements, 2008, 183 (2-3), pp.669 - 670. ⟨10.1080/10426500701796306⟩. ⟨hal-01580438⟩
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Wilfried-Solo Ojo, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo 2 Cp 2 (μ-SMe) 3 L 2 ] + (L = xylNC, t -BuNC, CO, MeCN). Organometallics, 2008, 27 (16), pp.4207 - 4222. ⟨10.1021/om8003702⟩. ⟨hal-01580480⟩
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2007

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Jean-François Capon, Salah Ezzaher, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electrochemical and theoretical investigations of the reduction of [Fe2(CO)5L{µ-SCH2XCH2S}] complexes related to [FeFe] hydrogenase. New Journal of Chemistry, 2007, 31 (12), ⟨10.1039/B709273C⟩. ⟨hal-01581409⟩
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Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Electron-Transfer-Catalyzed Rearrangement of Unsymmetrically Substituted Diiron Dithiolate Complexes Related to the Active Site of the [FeFe]-Hydrogenases. Inorganic Chemistry, 2007, 46 (23), pp.9863 - 9872. ⟨10.1021/ic701327w⟩. ⟨hal-01581411⟩
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Salah Ezzaher, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site Mimic. Inorganic Chemistry, 2007, 46 (9), pp.3426 - 3428. ⟨10.1021/ic0703124⟩. ⟨hal-01581352⟩
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Frederic Gloaguen, Didier Morvan, Jean-François Capon, Philippe P. Schollhammer, Jean Talarmin. Electrochemical proton reduction at mild potentials by monosubstituted diiron organometallic complexes bearing a benzenedithiolate bridge. Journal of Electroanalytical Chemistry, 2007, 603 (1), pp.15 - 20. ⟨10.1016/j.jelechem.2007.02.003⟩. ⟨hal-01581346⟩
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Alan Le Goff, Christine Leroy, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Formation of New μ-Thioalkylidene and μ-Borohydride Dimolybdenum Complexes from the μ-Alkylidyne Precursor [Mo 2 Cp 2 (μ-SMe) 3 (μ-CCH 2 Ph)]. Organometallics, 2007, 26 (14), pp.3607 - 3610. ⟨10.1021/om7003496⟩. ⟨hal-01581387⟩
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Alan Le Goff, Christine Leroy, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Influence of the initial bonding mode of the hydrocarbyl bridge on the mechanisms and products of the electrochemical reduction of alkyne- and vinylidene dimolybdenum tris(µ-thiolate) complexes. New Journal of Chemistry, 2007, 31 (2), pp.265 - 276. ⟨10.1039/B614948K⟩. ⟨hal-01581168⟩
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Didier Morvan, Jean-François Capon, Frederic Gloaguen, Alan Le Goff, Mathieu Marchivie, et al.. N-Heterocyclic Carbene Ligands in Nonsymmetric Diiron Models of Hydrogenase Active Sites. Organometallics, 2007, 26 (8), pp.2042 - 2052. ⟨10.1021/om061173l⟩. ⟨hal-01581322⟩
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Didier Morvan, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Electrochemical Synthesis of Mono- and Disubstituted Diiron Dithiolate Complexes as Models for the Active Site of Iron-Only Hydrogenases. European Journal of Inorganic Chemistry, 2007, 2007 (32), pp.5062 - 5068. ⟨10.1002/ejic.200700598⟩. ⟨hal-01581372⟩
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Wilfried-Solo Ojo, Jean-François Capon, Alan Le Goff, François Y. Pétillon, Philippe P. Schollhammer, et al.. Activation of propargylic alcohols by dimolybdenum tris(μ-thiolate) complexes: Influence of the substituents R in HCCCR2(OH)-vinylidene/allenylidene transformation. Reactivity of allenylidene complexes. Journal of Organometallic Chemistry, 2007, 692 (24), pp.5351 - 5367. ⟨10.1016/j.jorganchem.2007.08.023⟩. ⟨hal-01581394⟩
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Pierre-Yves Orain, Jean-François Capon, Nelly Kervarec, Frederic Gloaguen, François Y. Pétillon, et al.. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site. Dalton Transactions, 2007, 34, ⟨10.1039/B709287C⟩. ⟨hal-01581437⟩
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Vijendran Vijaikanth, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase. Journal of Organometallic Chemistry, 2007, 692 (19), pp.4177 - 4181. ⟨10.1016/j.jorganchem.2007.06.042⟩. ⟨hal-01581390⟩
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2006

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Nolwenn Cabon, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, Kenneth W. Muir. Methylation sites in tris(μ-thiolato)dimolybdenum(III) complexes. Journal of Organometallic Chemistry, 2006, 691 (4), pp.566 - 572. ⟨10.1016/j.jorganchem.2005.09.042⟩. ⟨hal-01582159⟩
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Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Activation of proton by the two-electron reduction of a di-iron organometallic complex. Journal of electroanalytical chemistry and interfacial electrochemistry, 2006, 595 (1), pp.47-52. ⟨10.1016/j.jelechem.2006.06.005⟩. ⟨hal-00700128⟩
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Alan Le Goff, Christine Leroy, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. Oxidatively-induced μ-η 1 → μ-η 1 :η 1 rearrangement of {NN} ligands at a {Mo 2 (μ-SMe) 3 } site and protonation of the oxidized diazenido complex. New Journal of Chemistry, 2006, 30 (6), pp.929 - 938. ⟨10.1039/B601377E⟩. ⟨hal-01582838⟩
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Christine Leroy, François Y. Pétillon, Kenneth W. Muir, Philippe P. Schollhammer, Jean Talarmin. Mixed μ-phosphido or μ-thiolato μ-halo-dimolybdenum(III) compounds [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] (X=PPh2, Y=Cl; X=SCH3, Y=Br, I): Electrochemical and structural comparisons – The X-ray structure of [{Mo2Cp2Br(μ-O)(μ-SMe)2}2(μ-MoO4)]. Journal of Organometallic Chemistry, 2006, 691 (5), pp.898 - 906. ⟨10.1016/j.jorganchem.2005.10.033⟩. ⟨hal-01582157⟩
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Wilfried-Solo Ojo, Eddy Paugam, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Formation of C−C, C−N, and C−O Links between Isonitrile, Cyclopentadienyl, and Hydroxide Ligands Bound to Molybdenum(III): Syntheses and Crystal Structures of μ-Aminocarbyne and μ-Amino-oxycarbene Dimolybdenum Complexes. Organometallics, 2006, 25 (16), pp.4009 - 4018. ⟨10.1021/om060383v⟩. ⟨hal-01582971⟩
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Wilfried-Solo Ojo, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, Kenneth W. Muir. A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization. Organometallics, 2006, 25 (22), pp.5503 - 5505. ⟨10.1021/om060663a⟩. ⟨hal-01582977⟩
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François Y. Pétillon, Françoise Robin-Le Guen, René Rumin, Philippe P. Schollhammer, Jean Talarmin, et al.. Reactions of [Fe3Cp2(CO)3(μ-CO)(μ3-CO)(μ3-CF3C2CF3)] with diphosphines: X-ray structure of a complex in which two tri-iron clusters are linked only by Ph2PCH2CH2PPh2. Journal of Organometallic Chemistry, 2006, 691 (12), pp.2853 - 2858. ⟨10.1016/j.jorganchem.2006.02.018⟩. ⟨hal-01582666⟩
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2005

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Nolwenn Cabon, A. Le Goff, Christine Leroy, François Pétillon, Philippe P. Schollhammer, et al.. Transformations and agostic interactions of hydrocarbyl ligands bonded to the sulfur-rich dimolybdenum site Mo2Cp2(μ-SMe) 3: Chemical and electrochemical formation of μ-alkyl and μ-vinyl compounds from a μ-alkylidene derivative. Organometallics, 2005, 24 (25), pp.6268-6278. ⟨10.1021/om050761g⟩. ⟨hal-01763766⟩
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Nolwenn Cabon, François Pétillon, Pierre Yves Orain, Philippe P. Schollhammer, Jean Talarmin, et al.. Controlled nucleophilic activation of different sites in [Mo 2Cp2L2(μ-SMe)2(μ-L′)] + cations (L = ButNC, xylNC, CO; L′ = SMe or PPh2). Journal of Organometallic Chemistry, 2005, 690 (21-22), pp.4583-4601. ⟨10.1016/j.jorganchem.2005.07.034⟩. ⟨hal-01763754⟩
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Jean-François Capon, S.E. Hassnaoui, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site. Organometallics, 2005, 24 (9), pp.2020-2022. ⟨10.1021/om049132h⟩. ⟨hal-01763739⟩
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Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Catalysis of the electrochemical H2 evolution by di-iron sub-site models. Coordination Chemistry Reviews, 2005, 249 (15-16 SPEC. ISS.), pp.1664-1676. ⟨10.1016/j.ccr.2004.11.018⟩. ⟨hal-01763762⟩
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M. Le Hénanf, C. Le Roy, François Pétillon, Philippe P. Schollhammer, Jean Talarmin. Nitrate- and nitrite-assisted conversion of an acetonitrile ligand into an amidato bridge at an Mo2(Cp)2(μ-SMe)3 core: Electrochemistry of the amidato complex [Mo2(Cp) 2(μ-SMe)3μ-η1,η1- OC(Me)NH]+. European Journal of Inorganic Chemistry, 2005, 19, pp.3875-3883. ⟨10.1002/ejic.200500315⟩. ⟨hal-01763758⟩
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V. Vijaikanth, Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Chemically modified electrode based on an organometallic model of the [FeFe] hydrogenase active center. Electrochemistry Communications, 2005, 7 (4), pp.427-430. ⟨10.1016/j.elecom.2005.02.019⟩. ⟨hal-01763738⟩
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2004

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Nolwenn Cabon, François Pétillon, Philippe P. Schollhammer, Jean Talarmin, K.W. Muir. Reaction of BH4- with Mo2Cp 2(μ-SMe)n species to give tetrahydroborato, hydrido or dimetallaborane compounds: Control of product by ancillary ligands. Dalton Transactions, 2004, 17, pp.2708-2719. ⟨10.1039/b407564a⟩. ⟨hal-01763874⟩
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Jean-François Capon, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. Electrochemical proton reduction by thiolate-bridged hexacarbonyldiiron clusters. Journal of Electroanalytical Chemistry, 2004, 566 (2), pp.241-247. ⟨10.1016/j.jelechem.2003.11.032⟩. ⟨hal-01763872⟩
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P. Das, Jean-François Capon, Frederic Gloaguen, François Pétillon, Philippe P. Schollhammer, et al.. Di-iron aza diphosphido complexes: Mimics for the active site of Fe-only hydrogenase, and effects of changing the coordinating atoms of the bridging ligand in [Fe2μ-(ECH2)2NR(CO)6]. Inorganic Chemistry, 2004, 43 (26), pp.8203-8205. ⟨10.1021/ic048772+⟩. ⟨hal-01763877⟩
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M. Le Hénanf, Christine Leroy, K.W. Muir, F.Y. Pétillon, Philippe P. Schollhammer, et al.. Electrochemical studies of complexes with oxo- or hydroxo-bridged Mo 2(μ-SMe)3+ centers: Cleavage of the oxygen bridge and generation of substrate-binding sites. European Journal of Inorganic Chemistry, 2004, 8, pp.1687-1700. ⟨10.1002/ejic.200300707⟩. ⟨hal-01763876⟩
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2003

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Nolwenn Cabon, E. Paugam, François Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Unexpected coupling of Cp and two RNC ligands at a Mo2(μ-SMe)3 nucleus. Organometallics, 2003, 22 (21), pp.4178-4180. ⟨10.1021/om030447r⟩. ⟨hal-01763900⟩
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Philippe P. Schollhammer, Nolwenn Cabon, A.-C. Kervella, François Pétillon, R. Rumin, et al.. Incorporation of alkyne and vinylidene ligands into tetrazolate groups at a sulfur-rich dimolybdenum site using sodium azide. Inorganica Chimica Acta, 2003, 350, pp.495-502. ⟨10.1016/S0020-1693(02)01556-6⟩. ⟨hal-01763906⟩
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2002

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N.L. Le Grand, K.W. Muir, François Pétillon, C.J. Pickett, Philippe P. Schollhammer, et al.. Electrochemical cleavage of N=N bonds at a Mo2(μ-SMe)3 site relevant to the biological reduction of dinitrogen at a bimetallic sulfur centre. Chemistry - A European Journal, 2002, 8, pp.3115--3127. ⟨10.1002/1521-3765(20020715)8:143115::AID-CHEM3115>3.0.CO;2-Z⟩. ⟨hal-01771333⟩
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Philippe P. Schollhammer, B. Didier, N. Le Grand, François Pétillon, J. Talarmin, et al.. Transformations of hydrazines RNHNH2 (R = Me, Ph) at a sulfur-rich bimetallic site: Diazene-diazenido-isodiazene/hydrazido(2-) interconversions. European Journal of Inorganic Chemistry, 2002, pp.658--663. ⟨hal-01771328⟩
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2001

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K.W. Muir, François Pétillon, R. Rumin, Philippe P. Schollhammer, J. Talarmin. Cis- and trans-Bis(1-phenyl-2,3,4,5-tetramethylphosphole)tetracarbonylmolybdenum(0), [Mo(CO)4(tmpPh)2]. Syntheses and structures. Journal of Organometallic Chemistry, 2001, 622 (1-2), pp.297-301. ⟨10.1016/S0022-328X(00)00874-3⟩. ⟨hal-01770130⟩
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Philippe P. Schollhammer, François Pétillon, Jean Talarmin, K.W. Muir. Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. Journal of Organometallic Chemistry, 2001, 627 (1), pp.67-70. ⟨10.1016/S0022-328X(01)00718-5⟩. ⟨hal-01770129⟩
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Philippe P. Schollhammer, M. Le Hénanf, C. Le Roy-Le Floch, François Pétillon, Jean Talarmin, et al.. Acetonitrile hydrationversusmolybdenum oxidation at the sulfur-rich bimetallic site MoIII2Cp2(μ-SMe)3 +. Crystal structure of the μ-η1 : η1-amidato complex[Mo2Cp2(μ-MeCONH)(μ-SMe)3]. Journal of the Chemical Society, Dalton Transactions, 2001, 10, pp.1573-1577. ⟨hal-01770141⟩
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Philippe P. Schollhammer, M. Le Hénanf, C. Le Roy-Le Floch, F.Y. Pétillon, J. Talarmin, et al.. Acetonitrile hydrationversusmolybdenum oxidation at the sulfur-rich bimetallic site {MoIII2Cp2(μ-SMe)3} +. Crystal structure of the μ-η1 η1-amidato complex[Mo2Cp2(μ-MeCONH)(μ-SMe)3]. Journal of the Chemical Society, Dalton Transactions, 2001, 10, pp.1573-1577. ⟨hal-02296664⟩
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Philippe P. Schollhammer, Nolwenn Cabon, Jean-François Capon, François Pétillon, Jean Talarmin, et al.. Activation of terminal alkynes at the sulfur-rich bimetallic site [MoIII2Cp2(μ-SMe)3]+: Alkyne-vinylidene conversion and C-S and C-C couplings promoted by addition of unsaturated substrates (RC≡CH, RN≡C, S=C=S).. Organometallics, 2001, 20 (6), pp.1230-1242. ⟨10.1021/om000966j⟩. ⟨hal-01770128⟩
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2000

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Jean Yves Cabon, Christine Leroy, K.W. Muir, François Pétillon, F. Quentel, et al.. Electrochemical reduction of a bridging imide: Generation of ammonia at a dimolybdenum tris(μ-thiolate) site. Chemistry - A European Journal, 2000, 6, pp.3033--3042. ⟨10.1002/1521-3765(20000818)6:163033::AID-CHEM3033>3.0.CO;2-A⟩. ⟨hal-01771375⟩
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Philippe P. Schollhammer, N. Cabon, F.Y. Petillon, J. Talarmin, K.W. Muir. Hydride transfer reactions in dimolybdenum compounds A simple route to the novel μ-η1 η1-tetrahydroboride complex [Mo2Cp2(μ-SMe)3(μ-BH4)]. Chemical Communications, 2000, 21, pp.2137-2138. ⟨10.1039/b006457m⟩. ⟨hal-02296670⟩
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1999

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J.-F. Capon, Philippe P. Schollhammer, François Pétillon, J. Talarmin, K.W. Muir. Novel μ-η2:η2 coordination of a thiophenium cation. Organometallics, 1999, 18, pp.2055--2057. ⟨hal-01771397⟩
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P. Madec, K.W. Muir, François Pétillon, R. Rumin, Y. Scaon, et al.. Generation of substrate-binding sites by electrochemical reduction of cis-[Fe2(cp)2(μ-SMe)2(MeCN)(L)]2+ (L = CO or MeCN). Reactivity of the sites toward CO and tBuNC. Crystal structure of [Fe2(cp)2(μ-SMe)2(CO)(MeCN)][BF 4]2·CH2Cl2. Journal of the Chemical Society - Dalton Transactions, 1999, pp.2371--2383. ⟨hal-01771399⟩
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François Pétillon, Philippe P. Schollhammer, Jean Talarmin, Kenneth Muir. Electrochemical Reduction of Nitrogenous Ligands at a Conserved Dinuclear Metal−Sulfur Site: Cleavage of the NN Bond of Phenyldiazene and Reduction of an Imide to NH 3. Inorganic Chemistry, 1999, 38 (9), pp.1954-1955. ⟨10.1021/ic9813359⟩. ⟨hal-02127137⟩
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Philippe P. Schollhammer, M. Pichon, K.W. Muir, François Pétillon, R. Pichon, et al.. A μ-η1-azavinylidene complex: Intramolecular condensation of two acetonitrile ligands at a dinuclear molybdenum(III) site. European Journal of Inorganic Chemistry, 1999, pp.221--223. ⟨hal-01771449⟩
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Philippe P. Schollhammer, François Pétillon, J. Talarmin, K.W. Muir. The effect of replacing carbonyl with acetonitrile on the reactivity of the bimetallic system [Mo2Cp2(μ-SMe)3(L)2]+ (L=CO, CH3CN). Crystal structure of [Mo2Cp2(μ-SMe)2(CH3CN) 4](BF4)2. Inorganica Chimica Acta, 1999, 284, pp.107--111. ⟨10.1016/S0020-1693(98)00266-7⟩. ⟨hal-01771400⟩
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1998

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François Pétillon, Philippe P. Schollhammer, J. Talarmin, K.W. Muir. Dinuclear molybdenum thiolato-bridged compounds: Syntheses, reactivities and electrochemical studies of site-substrate interactions. Coordination Chemistry Reviews, 1998, 178-180, pp.203--247. ⟨hal-01770742⟩
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Philippe P. Schollhammer, F.Y. Pétillon, J. Talarmin, K.W. Muir. A dimolybdenum(III) azido compound Its decomposition into amido and nitrido derivatives. Crystal structure of [Mo3(O)(N)Cp3(SMe)4]. Journal of Organometallic Chemistry, 1998, 560 (1-2), pp.245-251. ⟨10.1016/S0022-328X(98)00516-6⟩. ⟨hal-02296679⟩
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Philippe P. Schollhammer, Erwann Guenin, François Pétillon, Jean Talarmin, Kenneth Muir, et al.. η 1 −η 2 Rearrangement and Protonation of Phenyldiazo Bridging Ligands Attached to the Dimolybdenum System {Mo 2 Cp 2 (μ-SMe) 3 }. Organometallics, 1998, 17 (10), pp.1922-1924. ⟨10.1021/om971114v⟩. ⟨hal-02127136⟩
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1997

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François Pétillon, Philippe P. Schollhammer, Jean Talarmin. Electrochemical oxidation and protonation of a bridging amide ligand at a dinuclear metal-sulfur site. Journal of the Chemical Society - Dalton Transactions, 1997, pp.4019--4024. ⟨hal-01770532⟩
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F.Y. Pétillon, S. Poder-Guillou, Philippe P. Schollhammer, J. Talarmin. Influence of the C5R5 (R=H or Me) ring substituents on the electrochemistry of {Mo2(C5R5)2(μ-SR′) 2} complexes (R′=Me, Ph) and on the reactivity of electrogenerated intermediates with unsaturated substrates. New Journal of Chemistry, 1997, 21 (4), pp.477-494. ⟨hal-02296676⟩
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S. Poder-Guillou, Philippe P. Schollhammer, F.Y. Pétillon, J. Talarmin, K.W. Muir, et al.. Reactions of di- and poly-nuclear complexes. 17. Isolation and reactivity of μ-oxo dinuclear molybdenum(IV) thiolato-bridged complexes containing terminal and bridging chloride or bromide groups [(η-C5Me5)MoX]2(μ-X)(μ-O)(μ-SMe) (X = Cl, Br); crystal structure of [(η-C5Me5)MoBr]2(μ-Br)(μ-O)(μ-SMe). Inorganica Chimica Acta, 1997, 257 (2), pp.153-161. ⟨hal-02296671⟩
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Philippe P. Schollhammer, S. Poder-Guillou, F.Y. Pétillon, J. Talarmin. Substitution reactions in dinuclear molybdenum(III) thiolato-complexes induced by isocyanato ligands. Inorganica Chimica Acta, 1997, 261 (1), pp.117-120. ⟨10.1016/S0020-1693(96)05583-1⟩. ⟨hal-02296677⟩
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Philippe P. Schollhammer, E. Guénin, S. Poder-Guillou, F.Y. Pétillon, J. Talarmin, et al.. Reactions of dinuclear and polynuclear complexes. Part 18 substitution reactions of a μ-chloro or a μ-thiolato ligand in the dinuclear cyclopentadienyl molybdenum(III) complex [Cp2Mo2( μ-Cl)( μ-SMe)3]. Journal of Organometallic Chemistry, 1997, 539 (1-2), pp.193-199. ⟨10.1016/S0022-328X(97)00082-X⟩. ⟨hal-02296667⟩
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1996

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M.-L. Abasq, F.Y. Pétillon, Philippe P. Schollhammer, J. Talarmin. Electrochemical S-C bond cleavage in dimolybdenum thiolate/thioether- and bis(thioether)-bridged complexes. New Journal of Chemistry, 1996, 20 (12), pp.1221-1233. ⟨hal-02296673⟩
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Frédéric Barrière, Yves Le Mest, François Y. Pétillon, Sylvie Poder-Guillou, Philippe P. Schollhammer, et al.. Electrochemical deprotection of a substrate binding site in [Mo2(cp)2-(μ-SMe)3(μ-Cl)] (cp = η5-C5H5) via chloride-bridge opening. Kinetics of MeCN and ButNC binding at this site. Journal of the Chemical Society - Dalton Transactions, 1996, 20, pp.3967-3976. ⟨10.1039/DT9960003967⟩. ⟨hal-02296678⟩
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L.C. Mcdermott, K.W. Muir, F.Y. Pétillon, S. Poder-Guillou, Philippe P. Schollhammer. cis-(benzenethiolato)bis(tert-butyl isocyanide)carbonyl(cyclopentadienyl)-molybdenum(II), [Mo(C6H5S)(C5H9N) 2-(C5H5)(CO)]. Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], 1996, 52 (1), pp.74-77. ⟨10.1107/S0108270195009486⟩. ⟨hal-02296675⟩
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S. Poder-Guillou, Philippe P. Schollhammer, F.Y. Pétillon, J. Talarmin, S.E. Girdwood, et al.. Reactions of dinuclear and polynuclear complexes XV. Reinvestigation of the reaction between [CpMo(CO) 3H], allyl chloride and dimethyl disulfide Crystal structure of [(C5H5) Mo(CO)(μ-SMe) 3Mo(CO) 2(μ-SMe) Mo(CO) 2(C5H5)]. Journal of Organometallic Chemistry, 1996, 506 (1-2), pp.321-326. ⟨10.1016/0022-328X(95)05744-A⟩. ⟨hal-02296668⟩
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Philippe P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, K.W. Muir, et al.. Reactions of dinuclear and polynuclear complexes XVI. Chemistry of hydrido-, thiolato-bridged complexes [Mo2Cp2(μ-H)(μ-SR)(CO)4](R = Me, Ph) Reactivity and electrochemical behaviour; crystal structure of [Mo2Cp2(μ-SPh) {μ-ση2-C(CH3) =CHCH3}(CO)2]1. Journal of Organometallic Chemistry, 1996, 513 (1-2), pp.181-192. ⟨10.1016/0022-328X(95)05902-2⟩. ⟨hal-02296665⟩
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Philippe P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J.Y. Saillard, J. Talarmin, et al.. Disproportionation of hydrazine by [Mo2(η-C5H5) 2(μ-Cl)(μ-SMe)3] and formation of an Mo2(μ-NH2) amido bridge. Chemical Communications, 1996, 23, pp.2633-2634. ⟨10.1039/CC9960002633⟩. ⟨hal-02296674⟩
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1995

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Philippe P. Schollhammer, F.Y. Pétillon, R. Pichon, S. Poder-Guillou, J. Talarmin, et al.. Reactions of Di- and Polynuclear Complexes. 14. Synthesis of Permethylated-Cyclopentadienyl Chalcogeno-Bridged Compounds A Route to the Stable Thiolatosulfidocarbonyldimolybdenum(III) complex [Cp*2Mo2(CO)2(μ-SMe)2(μ-S)]. Crystal Structure Determination of [Cp*2Mo2(CO)2(μ-SMe)2(μ-SH)] [BF4]. Organometallics, 1995, 14 (5), pp.2277-2287. ⟨10.1021/om00005a029⟩. ⟨hal-02296669⟩
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Philippe P. Schollhammer, F.Y. Pétillon, R. Pichon, S. Poder-Guillou, J. Talarmin, et al.. Reactions of di- and poly-nuclear complexes 13. Synthesis, structure and fluxional behaviour of hydrido- and thiolato- or selenato-bridged complexes [Mo2Cp2(μ-H)(μ-ER)(CO)4] (E S, R Me, tBu, Bz, or Ph; E Se, R Ph). Journal of Organometallic Chemistry, 1995, 486 (1-2), pp.183-191. ⟨10.1016/0022-328X(94)05062-G⟩. ⟨hal-02296666⟩
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1991

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F.Y. Pétillon, Philippe P. Schollhammer, J. Talarmin. Reactions of di- and polynuclear complexes. VIII. Ligand substitution in [V2Cp2(CO)4(μ-SMe)2] by isocyanides or trimethyl phosphite. Synthesis, spectroscopic characterisation of the mono- and di-substituted derivatives. Electrochemical behaviour of the parent complex. Journal of Organometallic Chemistry, 1991, 411 (1-2), pp.159-170. ⟨10.1016/0022-328X(91)86015-I⟩. ⟨hal-02296672⟩
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Chapitre d'ouvrage

2013

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V. Artero, Frederic Gloaguen, M. Fontecave, Philippe P. Schollhammer. Biomasse : filière chimique bio-inspirée. R. Mosseri et C. Jeandel. L'énergie à découvert, CNRS Editions, pp.158-159, 2013. ⟨hal-01262161⟩
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2007

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François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. A few selected aspects of electrode-induced reactions at mono- and dinuclear molybdenum-sulfur centres.. A.J. Bard and M. Stratmann. Bard, Stratmann (Eds) : Encyclopedia of Electrochemistry, 3, WILEY-VCH, pp.567-589, 2007, Encyclopedia of electrochemistry (A.J. Bard and M. Stratmann eds), 3-527-30395-2. ⟨10.1002/9783527610426.bard070020⟩. ⟨hal-02127094⟩
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1993

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Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩
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N°spécial de revue/special issue

2008

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Philippe Schollhammer, Jean Talarmin. Bio-inspired hydrogen production/uptake catalysis. Comptes Rendus. Chimie, 11 (8), pp.789, 2008, ⟨10.1016/j.crci.2008.04.007⟩. ⟨hal-04108535⟩
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Autre publication scientifique

2008

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Jean‐françois Capon, Frédéric Gloaguen, François Pétillon, Philippe Schollhammer, Jean Talarmin. Organometallic Diiron Complex Chemistry Related to the [2Fe] H Subsite of [FeFe]H 2 ase (Eur. J. Inorg. Chem. 30/2008). 2008, pp.4659-4659. ⟨10.1002/ejic.200890083⟩. ⟨hal-04186855⟩
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Ouvrages

2014

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Wolfgang Weigand, Philippe P. Schollhammer. Bioinspired Catalysis, Metal-Sulfur Complexes. Wolfgang Weigand, Philippe Schollhammer. Wiley-VCH, 2014, 978-3-527-33308-0. ⟨hal-02127168⟩
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2008

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Philippe P. Schollhammer, Jean Talarmin. Bio-inspired hydrogen production/uptake catalysis. 11 (8), 2008, ⟨10.1016/j.crci.2008.04.007⟩. ⟨hal-01580484⟩
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